Tính pH trong dung dịch a. 4.6g Na vào 200ml nước b. Dd CH3COOH 0.01M biết α=12,5% c. Dd HClO 10^-3M biết α=0.13
Question
Lost your password? Please enter your email address. You will receive a link and will create a new password via email.
Answers ( )
a)
Phản ứng xảy ra:
\(2Na + 2{H_2}O\xrightarrow{{}}2NaOH + {H_2}\)
Ta có:
\({n_{Na}} = \frac{{4,6}}{{23}} = 0,2{\text{ mol = }}{{\text{n}}_{NaOH}} = {n_{O{H^ – }}} \to {\text{[O}}{{\text{H}}^ – }{\text{]}} = \frac{{0,2}}{{0,2}} = 1M \to pOH = – \log [O{H^ – }{\text{]}} = 0 \to pH = 14 – pOH = 14\)
b)
Cân bằng:
\(C{H_3}COOH\overset {} \leftrightarrows C{H_3}COO{^ – } + {H^ + }\)
Ta có:
\({\text{[}}{H^ + }{\text{]}} = {\text{[}}C{H_3}COO{H_{phân{\text{ ly}}}}{\text{]}} = 0,01.\alpha = 0,01.12,5\% = 0,00125M \to pH = – \log [{H^ + }{\text{]}} = 2,9\)
c) \(HClO\overset {} \leftrightarrows {H^ + } + Cl{O^ – }\)
\({\text{[}}{H^ + }{\text{]}} = {\text{[}}HCl{O_{phân{\text{ ly}}}}{\text{]}} = {10^{ – 3}}.\alpha = {10^{ – 3}}.0,13 = 0,00013M \to pH = – \log [{H^ + }] = 3,886\)