Cho 7.8g K tác dụng với 200g dung dịch al2(so4)3. 25% tinhs v h2 và m kết tủa 11/08/2021 Bởi Madelyn Cho 7.8g K tác dụng với 200g dung dịch al2(so4)3. 25% tinhs v h2 và m kết tủa
$n_K=\dfrac{7,8}{39}=0,2(mol)$ $n_{Al_2(SO_4)_3}=\dfrac{200.25\%}{342}=0,15(mol)$ $2K+2H_2O\to 2KOH+H_2$ $\Rightarrow n_{H_2}=\dfrac{n_{K}}{2}=0,1(mol)$ $V_{H_2}=0,1.22,4=2,24l$ $n_{KOH}=n_K=0,2(mol)$ $Al_2(SO_4)_3+6KOH\to 2Al(OH)_3+3K_2SO_4$ $\Rightarrow Al_2(SO_4)_3$ dư $n_{Al(OH)_3}=\dfrac{n_{KOH}}{3}=\dfrac{2}{30}(mol)$ $\to m_{\downarrow}=78.\dfrac{2}{30}=5,2g$ Bình luận
Đáp án: \({V_{{H_2}}} = 2,24l\) \({m_{Al{{(OH)}_3}}} = 5,2g\) Giải thích các bước giải: \(\begin{array}{l}K + {H_2}O \to KOH + \dfrac{1}{2}{H_2}\\6KOH + A{l_2}{(S{O_4})_3} \to 3{K_2}S{O_4} + 2Al{(OH)_3}\\{n_K} = 0,2mol\\ \to {n_{KOH}} = {n_K} = 0,2mol\\ \to {n_{{H_2}}} = \dfrac{1}{2}{n_K} = 0,1mol\\ \to {V_{{H_2}}} = 2,24l\\{m_{A{l_2}{{(S{O_4})}_3}}} = \dfrac{{200 \times 25}}{{100}} = 50g\\ \to {n_{A{l_2}{{(S{O_4})}_3}}} = 0,146mol\\ \to \dfrac{{{n_{KOH}}}}{6} < {n_{A{l_2}{{(S{O_4})}_3}}}\end{array}\) Suy ra \(A{l_2}{(S{O_4})_3}\) dư \(\begin{array}{l} \to {n_{Al{{(OH)}_3}}} = \dfrac{1}{3}{n_{KOH}} = \dfrac{{0,2}}{3}mol\\ \to {m_{Al{{(OH)}_3}}} = 5,2g\end{array}\) Bình luận
$n_K=\dfrac{7,8}{39}=0,2(mol)$
$n_{Al_2(SO_4)_3}=\dfrac{200.25\%}{342}=0,15(mol)$
$2K+2H_2O\to 2KOH+H_2$
$\Rightarrow n_{H_2}=\dfrac{n_{K}}{2}=0,1(mol)$
$V_{H_2}=0,1.22,4=2,24l$
$n_{KOH}=n_K=0,2(mol)$
$Al_2(SO_4)_3+6KOH\to 2Al(OH)_3+3K_2SO_4$
$\Rightarrow Al_2(SO_4)_3$ dư
$n_{Al(OH)_3}=\dfrac{n_{KOH}}{3}=\dfrac{2}{30}(mol)$
$\to m_{\downarrow}=78.\dfrac{2}{30}=5,2g$
Đáp án:
\({V_{{H_2}}} = 2,24l\)
\({m_{Al{{(OH)}_3}}} = 5,2g\)
Giải thích các bước giải:
\(\begin{array}{l}
K + {H_2}O \to KOH + \dfrac{1}{2}{H_2}\\
6KOH + A{l_2}{(S{O_4})_3} \to 3{K_2}S{O_4} + 2Al{(OH)_3}\\
{n_K} = 0,2mol\\
\to {n_{KOH}} = {n_K} = 0,2mol\\
\to {n_{{H_2}}} = \dfrac{1}{2}{n_K} = 0,1mol\\
\to {V_{{H_2}}} = 2,24l\\
{m_{A{l_2}{{(S{O_4})}_3}}} = \dfrac{{200 \times 25}}{{100}} = 50g\\
\to {n_{A{l_2}{{(S{O_4})}_3}}} = 0,146mol\\
\to \dfrac{{{n_{KOH}}}}{6} < {n_{A{l_2}{{(S{O_4})}_3}}}
\end{array}\)
Suy ra \(A{l_2}{(S{O_4})_3}\) dư
\(\begin{array}{l}
\to {n_{Al{{(OH)}_3}}} = \dfrac{1}{3}{n_{KOH}} = \dfrac{{0,2}}{3}mol\\
\to {m_{Al{{(OH)}_3}}} = 5,2g
\end{array}\)